This was not a light undertaking, but each new medication or routine I found would open up a little more energy and mental power to find the next key in the chain. Over the past year I’ve had major health struggles, but more importantly, I’ve done deep study of neuroscience, energy systems in the body, pharmacology, and developed a medical routine that lets me think and exist in a way that I have not in years. One example is wild encounters/monsters that overlap sections of graphics visually that they should not, this is due to a flaw in the world/collision system that is not easily altered. To this day minor bugs exist throughout the game that result from areas of the code that, if changed, would require rigorous testing of every area, and every feature. Regardless, I got to work and pushed out patches to fix major issues, and then the medium ones. Somewhere in the fog of it I lost the ability to properly assess the game, I would play and not experience bugs or glitches that others would report, release day was not a proud day for me, instead, it was wrought with confusion. With bouts of illness, I still am very proud to say that I was able to complete Monster Crown through random periods where a new medication would give me a month or so of near-normalcy, before sliding back to complete dysfunction.īut did Monster Crown reach completion in a way I’m proud of? As you can imagine, my life was in complete shambles, but Monster Crown continued. I even had significant bouts of amnesia that would leave me confused when even talking about the past day with my family. I was very, deeply sick, would regularly collapse, had to leave my job and would sleep for 16 hours, waking up even more tired than when I went to sleep. My eyes would not focus, my thumbs could not coordinate with my brain. This may seem like an unrelated tangent but when I became sick I could no longer jump over the first pit in the first level. I love Super Mario World, I have played it since I was 4 years old when my parents bought me a Super Nintendo, I even speedran it years ago and while I didn’t break any world records, I would come within 40 seconds of the world records for glitchless any%. While the cause and continuation of this chronic illness is unknown to me and my doctors, I have managed to create my own medical regime to mitigate its effects as much as possible. To be 100% clear, this is totally free DLC and will come in the form of an update for everyone.Īs most of you know, I was struck with an illness in 2019. Instead of releasing as three separate small packs, it will launch as one final “Content Pack” update, which might remind you of our schedule during Early Access. The DLC is sitting at about one third complete. We’ve had plenty of questions about our DLC plans, you’ll learn a little below about why the wait has been so long, but our plans to release DLC for Monster Crown in the near future remains the same. Storklift feather (warp back to a safe location)īest of luck finding these two new monsters! One can be found in Scarred Province, and another is out at sea waiting to find you.It’s been too long since I’ve seen you, and been too long since we had an update! Here’s what you can expect in today’s update: Today we launch version 1.0.5 of Monster Crown across Switch, PC, Linux and Mac. Sorry I can't specify the button that you use for it but in terms of getting the Hot Breeding option at least you'll now know where to go for it.Hello tamers! It’s me, devotedtoneurosis! I don't have the Switch version so I don't know the button prompt to change it, but when you are choosing the breed option there is a button prompt that will change it from standard breeding to Hot Breeding. There are also some.special combinations that you may get by fusing certain monsters.Īnyways, if you want to Hot Breed, you have to go back to the farm and use the breeding center there, as that one is used to give birth to monsters. This was designed more as a way to get the desired monster instantaneously without having to level it back up to the level your parent monsters were. The Hewston breeding is actually fusing two monsters together to get a new monster, getting rid of the parents in the process. Even though it says breeding what you actually do there is Fusion. If you're doing this in Hewston then you're in the wrong place. Originally posted by moonsilver445:I haven't figured out how to do this on the switch I have breeding unlocked and talked to the scientist.
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If you try this recipe, let us know! Leave a comment, rate it, and don’t forget to tag a photo Instagram. If you’re looking for an appetizer, try serving it with our Baked Plantain Chips & Garlicky Guacamole or Southwest Sweet Potato Black Bean Dip.Īnd for dessert? Try our Apple Butter Tamales or Easy Vegan Flan (No-Bake!)! Hungry yet? We are! More Easy + Hearty Dinner Recipes Ridiculously Easy Instant Pot Tuscan White Bean Soup. From here you can either stir the rice into the soup or add the rice to bowls and ladle the soup over the rice. Then add the chicken, the enchilada sauce, and broth. While plenty filling to be a meal on its own, this chicken tortilla soup would be delicious paired with our Crunchy Jicama Slaw or Chickpea Chopped Kale Salad with Adobo Dressing. Grab some rotisserie chicken to make this an easy camping recipe. Layer the onion, jalapeos, and garlic in the crockpot. We love this as an easy weeknight or make-ahead meal, and it also freezes well! What to Serve with Chicken Tortilla Soup We hope you LOVE this chicken tortilla soup! It’s: Garnish with tortilla chips and avocado (and optional radish and cilantro). A squeeze of lime adds just the right amount of brightness. If using the stovetop method, just make sure not to boil too vigorously or it can cause the chicken to become tough.įinish it off by stirring in some chopped greens (we like kale!) and adding the shredded chicken back in. These easy wraps (originally posted on The Half Baked Harvest blog) come together in minutes, theyre crunchy on the outside, and spicy and cheesy inside. Chicken broth provides the liquid to make it soupy and salt enhances all the flavors.Īfter cooking the chicken breasts in the Instant Pot, they become perfectly tender and easy to shred into bite-sized pieces using two forks. Shredded chicken, buffalo sauce, herbs, lettuce, and a little cheddar cheese, all folded up in wraps, then pan-fried until warm and crispy. Then we add canned fire-roasted diced tomatoes for ease, chicken breasts for protein, and black beans for a hearty fiber boost.Ĭanned chipotle peppers make this soup spicy and the adobo sauce they come in provides all that smoky flavor without any fuss. This 1-pot chicken tortilla soup recipe can be made in the Instant Pot or on the stovetop, but the Instant Pot is our preferred method because it makes the chicken especially tender.Įither way, it begins with a savory base of sautéd onion and garlic, plus cumin, chili powder, and oregano. For a more traditional version of sopa azteca, check out this recipe from La Piña en La Cocina. The following is our simplified version made with easy-to-access ingredients, a boost of greens, and tortilla chips for ease. Traditionally, it’s made with chicken broth, roasted tomatoes, onion, garlic, chiles, and tortillas. Tortilla soup (also known as sopa azteca) is believed to have originated in or near Mexico City. Pour Over: Grinding beans for a single cup and using a slow-pouring kettle to customize a coffee’s strength by varying the ratio of coffee to water. Micro Lot: Coffee harvested from a specific plot of land and processed separately to bring out the lot’s unique geographic characteristics.Ĭhemex: (Shown above) A one-piece, hourglass-shaped, nonporous, glass coffeemaker, which uses a specially designed filter, so no other flavors come through the coffee. A way to develop a palate.Įxtraction: The process of drawing flavor from coffee grounds. Cupping can teach about a roast’s profile or about the process of creating the coffee. A number of Westchester coffeehouse owners say it’s their drink of choice.Ĭupping: The art of learning, through aroma and taste, about coffee. Java-nology Want to consider yourself a coffee connoisseur? Know these terms.Ĭortado: A beverage that mixes equal parts espresso and warm, steamed milk, which reduces acidity. Ammirati loves when customers put themselves in the hands of the staff “to have a coffee experience.” He recommends adventurous coffee drinkers try a single-origin espresso or cortado. There’s a nod to the past with old-fashioned espresso makers on shelves and an eye toward the future with the café’s sleek espresso machine.Īmmirati’s passion is roasting (the café also handles wholesale accounts), and his roaster is “one of the, if not the most sustainable and efficient in the world,” he says. He’s taken that passion and opened this lovely space, decorated with black-and-white tiles, tables and chairs, plus a coffee bar where customers can stand and chat with the barista. As the third generation of his family in the coffee business, Joey Ammirati has coffee running through his veins. They appear with two lobes at a distance of 13.0 ± 0.1 Å (Fig. 2) allows individual isolated molecules to be investigated. 1).ĭeconstructing the islands molecule by molecule (Supplementary Fig. 1c) with ordering determined by the dipolar interaction between molecules (Supplementary Fig. Depositing these molecules onto a Ag(111) surface at room temperature, results in highly ordered honeycomb assemblies (Fig. To protect the polar groups from strong adsorption with the surface, DDNB contains two peripheral adamantane groups which allows for facile diffusion and interaction with the electric field 16. 1b) with a resulting net dipole moment of 6.78 Debye in the gas phase (see Supplementary Table 1). This arises from the electron-donating character of the dimethylamine (−N(CH 3) 2) and the electron-withdrawing properties of the nitro (−NO 2) group attached to the central benzene ring (Fig. We have developed the 2,5-di(ethynyladamantanyl)−4-(dimethylamino)nitrobenzene molecule (DDNB) 16 which, at its core, has a strong electric dipole. From these precision manipulation experiments, the electric field-induced motion can be mapped and used to determine the internal dipole moment of a single molecule. Here, we manipulate single dipolar molecules and obtain unidirectional rotation on demand, and thus deterministic behavior. In contrast to non-deterministic processes, we show that the electric field in an STM junction can be used to manipulate polar molecules with absolute precision (Fig. Molecular rotors in double-decker complexes have been rotated in large assemblies, albeit without control over the direction of rotation 15. While rotation is often combined with translation, e.g., along the edge of a molecular island 12, it can also be constrained to a fixed rotational axis 13, 14. Moreover, the STM tip has been used to induce rotation of various molecules 9, 10, 11. Scanning tunneling microscopy (STM) is attractive in this regard as it provides the means to image and manipulate matter at the single-molecule scale and track thermally induced processes like rotation and translation on metallic surfaces 8. Deterministically controlling the direction of molecular rotation and translation remains a challenge because numerous degrees of freedom exist and thermally activated processes offer little selectivity 7. Specifically, the orientation of a molecule or a functional group can affect many processes, for instance, molecular diffusion on a surface 1, 2, the efficiency of a chemical reaction 3, 4, and heterogeneous catalysis 5 or biochemical reactions with enzymes as catalyst 6. The coordinates are rotated 90 degrees around the Z axis. Z can be changed to X and Y to rotate around the X and Y axes, respectively.Controlling the motion and orientation of single molecules is key to the understanding of heterogeneous catalysis, growth and assembly processes as well as to the operation of surface-adsorbed molecular machines. If you want this bond to be parallel to other Cartesian axes, then follow the above method to first make this bond parallel to the X axis and then execute the following code. $sel move Īfter executing the above code, if you want to align bond between atom 3 and 5 to be parallel to the X axis then enter the following codeĪfter that, save the coordinate file. Copy the following code to VMD console and execute. Orient a certain bond parallel to a certain axisįirst load molecule’s structure file (such as. From Gaussian output file confirm dipole moment oreintation.xyz file to the gaussian input (.gjf) file and do single point energy calculation with the same orignal level of theory as of the optimized structure with an additional keyword nosymm. If the dipole moment vector of the molecule is (-6.5624 -3.2697 -2.1767), enter folowing commands in the VMD console to oreint the dipole moment vector along Z-axis.Then copy molecule coordinates from gaussian input file and paste in the new text file from 3rd line. xyz file format by creating a new text file and in this new file on the first line write the number of atoms in your molecule. Create Gaussian input file (.gjf) from the output file.Open output file in Gaussview and note dipole moment vector from results => charge distribution window).If you have Gaussian Output file of a molecule and want its dipole moment parallel to a certain axis for example Z-axis. Orient dipole moment parallel to a certain axis The easiest way to orient a certain vector or bond of a molecule parallel to Cartesian coordinate axis is to use the commands provided by VMD. Sometimes it is necessary to reorient the molecule to make its dipole moment or any other vector or certain bond of the molecule parallel to a certain Cartesian coordinate axis. |
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